2,6-Di-tert-butyl-4-mercaptophenol → HCID 20263297, compound

HRID 615265Notes

Reaction equation

HRID 615265 reaction equation
[C:1]([C:5]1[CH:10]=[C:9]([SH:11])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:4])([CH3:3])[CH3:2].[C:17]([O:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH3:48])(=[O:35])/[CH:18]=[CH:19]\[C:20]([O:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])=[O:21]>C(N(CC)CC)C>[C:1]([C:5]1[CH:10]=[C:9]([S:11][CH:18]([CH2:19][C:20]([O:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])=[O:21])[C:17]([O:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH3:48])=[O:35])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 703702,6-Di-tert-butyl-4-mercaptophenolHCID 5354846Didodecyl maleate

Product 1

HCID 20263297HCID 20263297, compound

Reagents, catalysts & solvents 1

HCID 8471TriethylamineSolvent

Procedure

The procedure of Example 1 is repeated using 7.15 grams of 2,6-di-tert-butyl-4-mercaptophenol, 13.58 grams of di-n-dodecyl maleate, and 0.3 gram of triethylamine. The product is purified by dry column chromatography to give a clear liquid.

Workup

  1. customThe product is purified
  2. customby dry column chromatography
  3. customto give a clear liquid

Sources & evidence

ORD record
ord-d01ad1cbfd4d4ce783cbcf2ffbc09c66
Source dataset
uspto-grants-1985_02
Patent number
US04497959

Reaction notes

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