HRID615423

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6641

Dicumyl peroxide

C18H22O2

HCID7904

Vinyl acetate

C4H6O2

$结构：CN1C(C)(C)CC(/C(C(=O)[O-])=C(\C(=O)[O-])C2CC(C)(C)N(C)C(C)(C)C2)CC1(C)C$

HCID86739024

未命名化合物

PRODUCTS

生成物

$结构：C=COC(C)=O.CN1C(C)(C)CC(/C(C(=O)[O-])=C(\C(=O)[O-])C2CC(C)(C)N(C)C(C)(C)C2)CC1(C)C$

HCID86739915

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1140

Toluene

C7H8

CONDITIONS

反应条件

温度: 120 °C

PROCEDURE

实验过程

Bis(1,2,2,6,6-pentamethyl-4-piperidyl)fumarate 2.1 g, vinyl acetate 1.7 g and dicumylperoxide 0.03 g were dissolved in 5 ml of toluene and stirred at 120° C. for five hours. The solvent and unreacted vinyl acetate were distilled off and a glassy solid was obtained. (Stabilizer No. I)

WORKUP

后处理

distillationThe solvent and unreacted vinyl acetate were distilled off
customa glassy solid was obtained

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-0a148a4080004a37b7fa349992d717af
来源数据集: uspto-grants-1985_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04499220
来源说明: uspto-grants-1985_02

反应 SMILES

[CH3:1][N:2]1[C:7]([CH3:9])([CH3:8])[CH2:6][CH:5](/[C:10](/[C:26]([O-:28])=[O:27])=[C:11](/[CH:15]2[CH2:20][C:19]([CH3:22])([CH3:21])[N:18]([CH3:23])[C:17]([CH3:25])([CH3:24])[CH2:16]2)\[C:12]([O-:14])=[O:13])[CH2:4][C:3]1([CH3:30])[CH3:29].[C:31]([O:34][CH:35]=[CH2:36])(=[O:33])[CH3:32].C(OOC(C1C=CC=CC=1)(C)C)(C1C=CC=CC=1)(C)C>C1(C)C=CC=CC=1>[CH3:23][N:18]1[C:19]([CH3:21])([CH3:22])[CH2:20][CH:15](/[C:11](/[C:12]([O-:14])=[O:13])=[C:10](/[CH:5]2[CH2:6][C:7]([CH3:8])([CH3:9])[N:2]([CH3:1])[C:3]([CH3:30])([CH3:29])[CH2:4]2)\[C:26]([O-:28])=[O:27])[CH2:16][C:17]1([CH3:25])[CH3:24].[C:31]([O:34][CH:35]=[CH2:36])(=[O:33])[CH3:32]