2-Ethylhexanol → HCID 54057365, compound

HRID 615676Notes

Reaction equation

HRID 615676 reaction equation
[S:1]([C:5]1[CH:16]=[CH:15][CH:14]=[CH:13][C:6]=1[C:7](OC(C)C)=[O:8])([OH:4])(=[O:3])=[O:2].[CH2:17]([CH:19]([CH2:22][CH2:23][CH2:24][CH3:25])[CH2:20][OH:21])[CH3:18]>C(O)(C)C>[S:1]([C:5]1[CH:16]=[CH:15][CH:14]=[CH:13][C:6]=1[C:7]([O:21][CH2:20][CH:19]([CH2:17][CH3:18])[CH2:22][CH2:23][CH2:24][CH3:25])=[O:8])([OH:4])(=[O:3])=[O:2]

Participants

4

Reactant 2

HCID 77202-EthylhexanolHCID 20447466HCID 20447466, compound

Product 1

HCID 54057365HCID 54057365, compound

Reagents, catalysts & solvents 1

HCID 3776IsopropanolSolvent

Procedure

Into a one-liter, four-necked round bottom flask equipped with a thermometer, distillation head, and glass stirrer with TEFLON paddle were charged 82.5 grams of 2-propyl o-sulfobenzoate solution in isopropanol and 100 grams of 2-ethylhexanol. The solution was vacuum distilled to a pot temperature of 105° C. and subsequently the vacuum was turned off and the reaction mixture held at 105° C. for one hour. The resultant 2-ethylhexyl o-sulfobenzoate was a brown liquid with an acid value of 102.

Workup

  1. distillationdistilled to a pot temperature of 105° C.

Sources & evidence

ORD record
ord-21ac0defae124d5ca4d7b00f738bb36e
Source dataset
uspto-grants-1985_02
Patent number
US04500680

Reaction notes

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