Chloroform → HCID 53959335, compound

HRID 615684Notes

Reaction equation

HRID 615684 reaction equation
[C:1]([S:9][C@@H:10]([CH2:26][S:27][C:28](=[O:35])[C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1)[C:11]([NH:13][C@H:14](C(N1CCC[C@H]1C(O)=O)=O)[CH3:15])=[O:12])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:36]([O:39]CC)(=[O:38])[CH3:37].[CH:42](Cl)(Cl)Cl>>[C:1]([S:9][C@H:10]([CH2:26][S:27][C:28](=[O:35])[C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1)[C:11]([N:13]1[CH2:14][CH2:15][CH2:42][C@H:37]1[C:36]([OH:39])=[O:38])=[O:12])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 3

HCID 6212ChloroformHCID 8857Ethyl AcetateHCID 53804224HCID 53804224, compound

Product 1

HCID 53959335HCID 53959335, compound

Procedure

N-[(R)-2,3-Bis-(benzoylthio)-propionyl]-alanylproline, melting point 195°-196° C. (ethyl acetate), Rf=0.40 in system I, [α]D20 =-125° (c=1 in chloroform).

Sources & evidence

ORD record
ord-c4fa4e70735d46d9816ea8e1531d6160
Source dataset
uspto-grants-1985_02
Patent number
US04500467

Reaction notes

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