HRID615901

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID10928

Ethyl chloroformate

C3H5ClO2

HCID14798

Sodium Hydroxide

HNaO

结构：CC1(C)CC(NCCCCCCNC2CC(C)(C)NC(C)(C)C2)CC(C)(C)N1

HCID93419

1,6-Bis(2,2,6,6-tetramethyl-4-piperidylamino)hexane

C24H50N4

PRODUCTS

生成物

结构：CCOC(=O)N(CCCCCCN(C(=O)OCC)C1CC(C)(C)NC(C)(C)C1)C1CC(C)(C)NC(C)(C)C1

HCID18998995

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

The N,N'-bis-(ethoxycarbonyl)-N,N'-bis-(2,2,6,6-tetramethyl-piperidin-4-yl)-hexamethylenediamine was prepared by reacting N,N'-bis-(2,2,6,6-tetramethyl-piperidin-4-yl)-hexamethylenediamine with ethyl chlorocarbonate in toluene in the presence of aqueous NaOH and was crystallised from octane.

WORKUP

后处理

customwas crystallised from octane

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-75a852042da1470b858a622f8fc14518
来源数据集: uspto-grants-1985_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04501837
来源说明: uspto-grants-1985_02

反应 SMILES

[CH3:1][C:2]1([CH3:28])[CH2:7][CH:6]([NH:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][NH:15][CH:16]2[CH2:21][C:20]([CH3:23])([CH3:22])[NH:19][C:18]([CH3:25])([CH3:24])[CH2:17]2)[CH2:5][C:4]([CH3:27])([CH3:26])[NH:3]1.[C:29](Cl)(=[O:33])[O:30][CH2:31][CH3:32].[OH-:35].[Na+]>C1(C)C=CC=CC=1>[CH2:31]([O:30][C:29]([N:8]([CH:6]1[CH2:7][C:2]([CH3:28])([CH3:1])[NH:3][C:4]([CH3:27])([CH3:26])[CH2:5]1)[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][N:15]([C:29]([O:30][CH2:31][CH3:32])=[O:35])[CH:16]1[CH2:17][C:18]([CH3:25])([CH3:24])[NH:19][C:20]([CH3:23])([CH3:22])[CH2:21]1)=[O:33])[CH3:32]