Methanol → 2-Nitro-4-(propane-1-sulfinyl)aniline

HRID 616078Notes

Reaction equation

HRID 616078 reaction equation
C([NH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11]([CH2:13][CH2:14][CH3:15])=[O:12])=[CH:7][C:6]=1[N+:16]([O-:18])=[O:17])(=O)C.[OH-].[Na+].CO>O>[NH2:4][C:5]1[CH:10]=[CH:9][C:8]([S:11]([CH2:13][CH2:14][CH3:15])=[O:12])=[CH:7][C:6]=1[N+:16]([O-:18])=[O:17]

Participants

5

Reactant 3

HCID 887MethanolHCID 14798Sodium HydroxideHCID 20371008HCID 20371008, compound

Product 1

HCID 203628252-Nitro-4-(propane-1-sulfinyl)aniline

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

1.5 G. of 1-acetamido-2-nitro-4-n-propylsulfinylbenzene is treated with 3 ml. of 5N sodium hydroxide solution and sufficient methanol to effect solution. After heating on a steam bath for 15 minutes, the mixture is diluted with water, cooled and filtered, yielding 1-amino-2-nitro-4-n-propylsulfinylbenzene.

Workup

  1. temperatureAfter heating on a steam bath for 15 minutes
  2. temperaturecooled
  3. filtrationfiltered

Sources & evidence

ORD record
ord-d4453324c7444c0da936d3fe495a7343
Source dataset
uspto-grants-1978_02
Patent number
US04072696

Reaction notes

Loading…