Hydrochloric Acid → 4-Amino-3-nitrophenyl thiocyanate

HRID 616081Notes

Reaction equation

HRID 616081 reaction equation
C([NH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11][C:12]#[N:13])=[CH:7][C:6]=1[N+:14]([O-:16])=[O:15])(=O)C.Cl.CO>O>[NH2:4][C:5]1[CH:10]=[CH:9][C:8]([S:11][C:12]#[N:13])=[CH:7][C:6]=1[N+:14]([O-:16])=[O:15]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 887MethanolHCID 8180927Thiocyanic acid, 4-(acetylamino)-3-nitrophenyl ester

Product 1

HCID 1046774-Amino-3-nitrophenyl thiocyanate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

6 G. of 1-acetamido-2-nitro-4-thiocyanatobenzene is suspended in a mixture of 30 ml. concentrated hydrochloric acid and 30 ml. methanol, and the mixture stirred at room temperature for 24 hours. The water is added and the product isolated by filtration, yielding 1-amino-2-nitro-4-thiocyanatobenzene.

Workup

  1. customthe product isolated by filtration

Sources & evidence

ORD record
ord-bc999e2d1c2348beade67f08a5f504a8
Source dataset
uspto-grants-1978_02
Patent number
US04072696

Reaction notes

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