Methanol → HCID 20370997, compound

Participants

Reaction Steps

1.5 G. of 1-(3-methoxycarbonyl-2-thioureido)-2-nitro-4-(prop-2-en-1-ylthio)benzene is treated for four hours in a refluxing mixture of 160 ml. methanol and 40 ml. water with 4 g. iron powder (added in two portions) and 1 g. ferrous sulfate. The mixture is filtered, and the filtrate concentrated. The residue is dissolved in chloroform and washed with water, and then the solvent is evaporated affording 1-(3-methoxycarbonyl-2-thioureido)-2-amino-4-(prop-2-en-1-yl-thio)benzene.

Provenance & Evidence