HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl heptanoate → 5-Hexylthiomethyl-2-oxo-cyclopentanecarboxylic acid methyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl heptanoate | HCID 7826 | — |
| Reactant | 1-Hexanethiol | HCID 8106 | — |
| Reactant | Potassium tert-butoxide | HCID 23665647 | — |
| Product | 5-Hexylthiomethyl-2-oxo-cyclopentanecarboxylic acid methyl ester | HCID 54239364 | 61.3% |
Reaction Steps
In accordance with the process of Example 17, potassium t-butoxide, (336 mg; 3 m mol), n-hexyl mercaptan (354 mg; 3 m mol) and 2-oxo-bicyclo 3.1.0!hexane-1-carboxylic acid methyl ester (463 mg; 3 m mol) were used to obtain 500 mg of 5-hexylthiomethyl-2-oxo-cyclopentanecarboxylic acid methyl ester.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04073799 |
| Source dataset | uspto-grants-1978_02 |
| ORD ID | ord-6813b7b5544b483e9e3dd6ffc96b5d32 |
| Source note | uspto-grants-1978_02 |