m-Chloroperbenzoic acid → HCID 54217344, compound

HRID 616300Notes

Reaction equation

HRID 616300 reaction equation
[CH3:1][O:2][C:3](=[O:24])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]1[CH:14]([CH2:15][S:16][C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)[CH2:13][CH2:12][C:11]1=[O:23].ClC1C=CC=C(C(OO)=[O:33])C=1>>[CH3:1][O:2][C:3](=[O:24])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]1[CH:14]([CH2:15][S:16]([C:17]2[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=2)=[O:33])[CH2:13][CH2:12][C:11]1=[O:23]

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 70619976Methyl 7-{2-oxo-5-[(phenylsulfanyl)methyl]cyclopentyl}heptanoate

Product 1

HCID 54217344HCID 54217344, compoundYield 85%

Procedure

In accordance with the process of Example 29, 2-oxo-5-phenylthiomethyl-cyclopentaneheptanoic acid methyl ester of Example 27 (890 mg; 2.58 m mol) and m-chloroperbenzoic acid having a purity of 85% (5.25 mg; 2.58 m mol) were used to obtain 800 mg of 5-benzenesulfinylmethyl-2-oxo-cyclopentaneheptanoic acid methyl ester as viscous oil.

Sources & evidence

ORD record
ord-2e5e3f33798a4f4c9a317adcacf45d1f
Source dataset
uspto-grants-1978_02
Patent number
US04073799

Reaction notes

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