Hydrogen Peroxide → HCID 54135682, compound

HRID 616337Notes

Reaction equation

HRID 616337 reaction equation
[OH:1]O.[CH3:3][S:4][CH2:5][CH2:6][NH:7][C:8]([NH2:10])=[O:9]>C(O)C.C(O)=O>[CH3:3][S:4]([CH2:5][CH2:6][NH:7][C:8]([NH2:10])=[O:9])=[O:1]

Participants

5

Reactant 2

HCID 784Hydrogen PeroxideHCID 2485401-[2-(methylsulfanyl)ethyl]urea

Product 1

HCID 54135682HCID 54135682, compoundYield 85%

Reagents, catalysts & solvents 2

HCID 284Formic AcidSolventHCID 702EthanolSolvent

Procedure

There are slowly added 3 ml of H2O2 (110 volumes) to a well agitated solution of 20 moles of 2-methylthio ethylurea in a mixture of ethanol and formic acid. The solution obtained is agitated for 2 hours after which it is concentrated under reduced pressure. The resulting residue is then crystallized in ethylacetate thus providing white crystals melting at 88° C. in a yield of 85%.

Workup

  1. customThe solution obtained
  2. concentrationis concentrated under reduced pressure
  3. customThe resulting residue is then crystallized in ethylacetate

Sources & evidence

ORD record
ord-d307a2c39cf6428fa5991b5360358c4d
Source dataset
uspto-grants-1978_02
Patent number
US04073898

Reaction notes

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