Nitrogen fluoride (N2F4) → 1,1,1,3,3,3-Hexafluoro-2-{[1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-yl]peroxy}-2-(trifluoromethyl)propane

HRID 616520Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 616520
F[O:2][C:3]([C:12]([F:15])([F:14])[F:13])([C:8]([F:11])([F:10])[F:9])[C:4]([F:7])([F:6])[F:5].FN(F)N(F)F>>[F:5][C:4]([F:7])([F:6])[C:3]([O:2][O:2][C:3]([C:4]([F:5])([F:6])[F:7])([C:12]([F:13])([F:15])[F:14])[C:8]([F:11])([F:10])[F:9])([C:12]([F:15])([F:14])[F:13])[C:8]([F:11])([F:10])[F:9]

Komponenten

3

Edukt 2

HCID 24845Nitrogen fluoride (N2F4)HCID 23233496HCID 23233496, Verbindung

Produkt 1

HCID 232351261,1,1,3,3,3-Hexafluoro-2-{[1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-yl]peroxy}-2-(trifluoromethyl)propane

Versuchsvorschrift

In accordance with this invention, it has been found that the above-described objects can be accomplished by effecting a photolytic reaction between equimolar amounts of perfluoro-t-butyl hypofluorite and tetrafluorohydrazine. The resulting volatile reaction product, NF3, is evacuated at -90° C leaving a pure bis(perfluoro-t-butyl) peroxide residue.

Aufarbeitung

  1. customThe resulting volatile reaction product, NF3, is evacuated at -90° C

Quellen und Nachweise

ORD-Eintrag
ord-a98b4926d5524b71aed989f67578e855
Quelldatensatz
uspto-grants-1978_02
Patentnummer
US04075073

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