HuagongsheHuagongshe Chemistry Print Report · For research reference only
Magnesium ethanolate → CID 11066066
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Magnesium ethanolate | HCID 164963 | — |
| Reactant | Propanedioic acid, monoethyl ester | HCID 3595298 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | CID 11066066 | HCID 11066066 | 95.8% |
Reaction Steps
Magnesium ethyl malonate was prepared as follows: To a stirred THF solution (1 L) of monoethyl malonate (183.18 g, 1.39 mol) was added magnesium ethoxide (79.54 g, 0.70 mol) in several portions. After about 4 hours, the solvent was removed under reduced pressure and the residue was reevaporated with toluene to give magnesium ethyl malonate (190.82 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05948786 |
| Source dataset | uspto-grants-1999_09 |
| ORD ID | ord-1b895215a47345c1a72880cfa768901a |
| Source note | uspto-grants-1999_09 |