Hydrochloric Acid → HCID 12393363, compound

HRID 617643Notes

Reaction equation

[N+:1]([C:4]1[CH:11]=[CH:10][C:7]([C:8]#[N:9])=[CH:6][CH:5]=1)([O-:3])=[O:2].[ClH:12].[CH2:13]([OH:15])[CH3:14]>>[ClH:12].[N+:1]([C:4]1[CH:5]=[CH:6][C:7]([C:8](=[NH:9])[O:15][CH2:13][CH3:14])=[CH:10][CH:11]=1)([O-:3])=[O:2]

Participants

Reactant 3

HCID 313Hydrochloric Acid

HCID 702Ethanol

HCID 120904-Nitrobenzonitrile

Product 1

HCID 12393363HCID 12393363, compound

Procedure

Ethyl 4-nitrobenzimidate hydrochloride was synthesized in the same manner as in Reference Example 2. That is, 4-nitrobenzonitrile (26.5 g, 0.179 mol) was reacted with hydrogen chloride in ethanol (250 mL) to give 35.7 g (86%) of the target compound as colorless crystals.

Sources & evidence

ORD record: ord-8e2c8aa882114a9b942f2532b5b5cb53
Source dataset: uspto-grants-1999_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05948785

Reaction notes

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