N-acetyl-beta-D-glucosaminyl-(1->4)-N-acetyl-aldehydo-D-glucosamine → HCID 53825897, compound

HRID 618619Notes

Reaction equation

HRID 618619 reaction equation
CC([NH:4][C@H:5]1[C@H:10]([O:11][C@@H:12]([C@H:17]([OH:25])[C@@H:18]([NH:21][C:22]([CH3:24])=[O:23])[CH:19]=[O:20])[C@H:13]([OH:16])[CH2:14][OH:15])[O:9][C@H:8]([CH2:26][OH:27])[C@@H:7]([OH:28])[C@@H:6]1[OH:29])=O.C(N[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O)(=O)C>>[C:22]([NH:21][C@H:18]([C@H:17]([C@@H:12]([C@@H:13]([CH2:14][OH:15])[OH:16])[O:11][C@@H:10]1[O:9][C@H:8]([CH2:26][OH:27])[C@@H:7]([OH:28])[C@H:6]([OH:29])[C@H:5]1[NH2:4])[OH:25])[CH:19]=[O:20])(=[O:23])[CH3:24]

Participants

3

Reactant 2

HCID 160244N-acetyl-beta-D-glucosaminyl-(1->4)-N-acetyl-aldehydo-D-glucosamine2×HCID 439174N-Acetyl-D-Glucosamine

Product 1

HCID 53825897HCID 53825897, compound

Procedure

This enzyme is reacted with the starting compound, di-N-acetylchitobiose, whereby only the acetyl group of the N-acetylglucosamine residue positioned at the non-reducing terminal of said di-N-acetylchitobiose is removed to convert said residue to a glucosamine residue, thereby obtaining the intended product, 2-acetylamino-4-O-(2-amino-2-deoxy-β-D-glucopyranosyl)-2-deoxy-D-glucose.

Workup

  1. customis removed

Sources & evidence

ORD record
ord-cb47a33db2cb43218743dc1a314bf799
Source dataset
uspto-grants-1999_09
Patent number
US05955320

Reaction notes

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