(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal → Glucose glycerol

HRID 618622Notes

Reaction equation

HRID 618622 reaction equation
[O:1]=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4]>OCC(CO)O>[O:1]=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[OH:1][CH2:2][CH:3]([CH2:5][OH:6])[OH:4]

Participants

3

Reactant 1

HCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

Product 1

HCID 87178496Glucose glycerol

Reagents, catalysts & solvents 1

HCID 753GlycerolSolvent

Procedure

About 475 g. of glycerol is placed in a 2000 ml beaker and heated on a hot plate while stirring. About 525 g. of glucose is then added to the beaker.

Workup

  1. temperatureheated on a hot plate

Sources & evidence

ORD record
ord-51dc54769ac6449582aac601ac46d962
Source dataset
uspto-grants-1999_09
Patent number
US05955419

Reaction notes

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