HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → 1-Adamantanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Adamantane | HCID 9238 | — |
| Reactant | N-Hydroxyphthalimide | HCID 10665 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | Adamantanone | HCID 64151 | 4% |
| Product | 1-Adamantanol | HCID 64152 | 50% |
Reaction Steps
To 25 milliliters of acetic acid were added 10 millimoles of adamantane, 1 millimole of N-hydroxyphthalimide and 0.05 millimole of acetylacetonatocopper(II) Cu(AA)2. In an oxygen atmosphere, the resultant mixture was stirred at a temperature of 75° C. for 6 hours. Adamantane was transformed, with a transformation rate of 53%, into 1-adamantanol (yield 50%) and 2-adamantanone (yield 4%). The selectivity for the alcohol and ketone was 97%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05958821 |
| Source dataset | uspto-grants-1999_09 |
| ORD ID | ord-c2cd220e33a145aebf42eb1eeaeff962 |
| Source note | uspto-grants-1999_09 |