HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → Fluoreneone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Fluorene | HCID 6853 | — |
| Reactant | N-Hydroxyphthalimide | HCID 10665 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | Fluoreneone | HCID 22281833 | 48% |
Reaction Steps
A mixture of 10 millimoles of fluorene, 1 millimole of N-hydroxyphthalimide, 0.05 millimole of acetylacetonatovanadium V(AA)3 and 25 milliliters of acetic acid was stirred, in an oxygen atmosphere, at a temperature of 90° C. for 6 hours. In analyzing a product in the reaction mixture by gas chromatography, fluorene was transformed into fluorenone (yield 48%) with a transformation rate of 54 percent.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05958821 |
| Source dataset | uspto-grants-1999_09 |
| ORD ID | ord-f90cac379be046ffa0c42c8c19180556 |
| Source note | uspto-grants-1999_09 |