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HRID619870

反应详情

EQUATION

反应方程式

HRID 619870 的结构方程式

REACTANTS

反应物

2
结构：CO[C@H]1OC(CO)[C@H](O)[C@@H](O)[C@@H]1O
HCID76607

未命名化合物

结构：O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
HCID107526

未命名化合物

PRODUCTS

生成物

1
结构：CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O
HCID93321

Dodecyl glucoside

C18H36O6

CONDITIONS

反应条件

温度
120 °C

PROCEDURE

实验过程

The insoluble material was filtered, washed with Skellysolve B® solvent, a hydrocarbon solvent boiling in the range of 60° to 70° C., and then dried by heating at 120° C. at a pressure of about 4 mm. mercury. The dry material, which had a mass of 20.15 g., was analyzed by liquid chromatography and was found to contain approximately 88 weight percent methyl polyglucoside. This corresponds to approximately 0.11 moles of glucose units using the following conversion: ##EQU1## Therefore, of the 0.14 moles of methyl glucoside initially present, approximately 0.11 moles (or 79 percent) formed methyl polyglucoside rather than the desired dodecyl glucoside.

WORKUP

后处理

  1. filtrationThe insoluble material was filtered
  2. washwashed with Skellysolve B® solvent
  3. customboiling in the range of 60° to 70° C.
  4. customdried