Potassium Carbonate → HCID 14695643, compound

HRID 619894Notes

Reaction equation

HRID 619894 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([O:9]C(OC)=O)=[CH:4][C:3]=1[N:14]1[C:18](=[O:19])[C:17](=[C:20]([CH3:22])[CH3:21])[O:16][C:15]1=[O:23].ClC1C=C(Cl)C(OC(OC)=O)=CC=1[N+]([O-])=O.C(=O)([O-])[O-].[K+].[K+]>CO>[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([OH:9])=[CH:4][C:3]=1[N:14]1[C:18](=[O:19])[C:17](=[C:20]([CH3:21])[CH3:22])[O:16][C:15]1=[O:23]

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 14695641HCID 14695641, compoundHCID 14695642HCID 14695642, compound

Product 1

HCID 14695643HCID 14695643, compoundYield 56.9%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

To a dried methanol solution (100 ml) of 3-(2',4'-dichloro-5'-methoxycarbonyloxyphenyl)-5-isopropylidene-1,3-oxazolidine-2,4-dione (3.60 g, 10 mmol), which was synthesized from 2,4-dichloro-5-methoxycarbonyloxy nitrobenzene as a starting material in a method similar to that shown in Reference Example 6, 9, 10 and 4, was added potassium carbonate (0.69 g, 5 mmol) and the mixture was heated under reflux for 2 hours. 3-(2',4'-dichloro-5'-hydroxyphenyl)-5-isopropylidene-1,3-oxazolidine-2,4-dione (1.72 g) was obtained by a treatment similar to that in Reference Example 1.

Workup

  1. temperaturethe mixture was heated
  2. temperatureunder reflux for 2 hours

Sources & evidence

ORD record
ord-acd2d976d42b4ed5a61d6ed1bfdeef18
Source dataset
uspto-grants-1989_04
Patent number
US04818272

Reaction notes

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