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HRID620454

反应详情

EQUATION

反应方程式

HRID 620454 的结构方程式

REACTANTS

反应物

3
结构：CC(C)(C#N)N=NC(C)(C)C#N
HCID6547

Azobisisobutyronitrile

C8H12N4

结构：CC(C)=C[C@@H]1[C@H](C(=O)O)C1(C)C
HCID20755

Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-, (1S,3R)-

C10H16O2

结构：BrBr
HCID24408

Bromine

Br2

PRODUCTS

生成物

1
结构：CC(C)=CC1C(C(=O)O)C1(C)C
HCID2743

Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-

C10H16O2

收率 95.5%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

结构：ClC(Cl)(Cl)Cl
溶剂HCID5943

Carbon tetrachloride

CCl4

CONDITIONS

反应条件

温度
80 °C

PROCEDURE

实验过程

2.0 g of cis-chrysanthemic acid and 23 mg of azobisisobutyronitrile were dissolved in 20 ml of toluene and thereto was added dropwise a solution of bromine (21 mg) in carbon tetrachloride with stirring at 80° C. over a period of 20 minutes. Thereafter, a treatment similar to Example 1 was carried out to obtain 1.91 g of chrysanthemic acid. Gas chromatographic assay thereof showed the composition: cis, 9.8% and trans, 90.2%.