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HRID620455

反应详情

EQUATION

反应方程式

HRID 620455 的结构方程式

REACTANTS

反应物

3
结构：CC(C)(C#N)N=NC(C)(C)C#N
HCID6547

Azobisisobutyronitrile

C8H12N4

结构：CC(=O)Br
HCID10482

Acetyl bromide

C2H3BrO

结构：CC(C)=C[C@@H]1[C@H](C(=O)O)C1(C)C
HCID20755

Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-, (1S,3R)-

C10H16O2

PRODUCTS

生成物

1
结构：CC(C)=CC1C(C(=O)O)C1(C)C
HCID2743

Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-

C10H16O2

收率 92%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

2 次

CONDITIONS

反应条件

温度
80 °C

PROCEDURE

实验过程

5.0 g of cis-chrysanthemic acid and 0.2 g of azobisisobutyronitrile were dissolved in 50 ml of toluene and thereto was added dropwise a solution of acetyl bromide (55 mg) in toluene with stirring at 80° C. over a period of 20 minutes. Then, the same treatment as in Example 1 was effected to obtain 4.6 g of chrysanthemic acid. The IR spectrum thereof was identical with that of chrysanthemic acid.