HCID 19860676, compound → HCID 20085850, compound

HRID 620466Notes

Reaction equation

HRID 620466 reaction equation
[N+:1]([C:4]1[CH:27]=[CH:26][C:7]([O:8][CH2:9][C:10]([CH2:24][CH3:25])([CH2:22][CH3:23])[CH2:11][O:12][C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-])=O)=[CH:15][CH:14]=2)=[CH:6][CH:5]=1)([O-])=O>CN(C=O)C.[Ni]>[NH2:19][C:16]1[CH:15]=[CH:14][C:13]([O:12][CH2:11][C:10]([CH2:22][CH3:23])([CH2:24][CH3:25])[CH2:9][O:8][C:7]2[CH:26]=[CH:27][C:4]([NH2:1])=[CH:5][CH:6]=2)=[CH:18][CH:17]=1

Participants

4

Reactant 1

HCID 19860676HCID 19860676, compound

Product 1

HCID 20085850HCID 20085850, compound

Reagents, catalysts & solvents 2

HCID 935NickelCatalystHCID 6228DimethylformamideSolvent

Procedure

270 g 1,3-bis-(4-nitrophenoxy)-2,2-diethylpropane were hydrogenated by the same procedure as that of Example 10 in 1400 l DMF in the presence of 42 g Raney nickel. The crude product was recrystallized from isopropanol.

Workup

  1. customThe crude product was recrystallized from isopropanol

Sources & evidence

ORD record
ord-673aaaa2d3b348e393b11efa2356ad6d
Source dataset
uspto-grants-1989_04
Patent number
US04820866

Reaction notes

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