1,3-Bis(4-nitrophenoxy)-2,2,4-trimethylpentane → 1,3-Bis-(4-aminophenoxy)-2,2,4-trimethylpentane

HRID 620468Notes

Reaction equation

HRID 620468 reaction equation
[N+:1]([C:4]1[CH:28]=[CH:27][C:7]([O:8][CH2:9][C:10]([CH3:26])([CH3:25])[CH:11]([O:15][C:16]2[CH:21]=[CH:20][C:19]([N+:22]([O-])=O)=[CH:18][CH:17]=2)[CH:12]([CH3:14])[CH3:13])=[CH:6][CH:5]=1)([O-])=O>CN(C=O)C.[Ni]>[NH2:1][C:4]1[CH:5]=[CH:6][C:7]([O:8][CH2:9][C:10]([CH3:26])([CH3:25])[CH:11]([O:15][C:16]2[CH:17]=[CH:18][C:19]([NH2:22])=[CH:20][CH:21]=2)[CH:12]([CH3:14])[CH3:13])=[CH:27][CH:28]=1

Participants

4

Reactant 1

HCID 198606781,3-Bis(4-nitrophenoxy)-2,2,4-trimethylpentane

Product 1

HCID 198606771,3-Bis-(4-aminophenoxy)-2,2,4-trimethylpentane

Reagents, catalysts & solvents 2

HCID 935NickelCatalystHCID 6228DimethylformamideSolvent

Procedure

250 g 1,3-bis-(4-nitrophenoxy)-2,2,4-trimethyl-pentane were hydrogenated as in Example 10 in 1300 ml DMF in the presence of 39 g Raney nickel.

Sources & evidence

ORD record
ord-d928faabe4084003a5d4a30a654e24ad
Source dataset
uspto-grants-1989_04
Patent number
US04820866

Reaction notes

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