Thionyl Chloride → 2-(4-nitrophenoxy)tetradecanoyl Chloride

HRID 620703Notes

Reaction equation

HRID 620703 reaction equation
[N+:1]([C:4]1[CH:26]=[CH:25][C:7]([O:8][CH:9]([CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[C:10](O)=[O:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].S(Cl)([Cl:29])=O>>[N+:1]([C:4]1[CH:26]=[CH:25][C:7]([O:8][CH:9]([CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[C:10]([Cl:29])=[O:11])=[CH:6][CH:5]=1)([O-:3])=[O:2]

Participants

3

Reactant 2

HCID 24386Thionyl ChlorideHCID 37465002-(4-nitrophenoxy)-Tetradecanoic acid

Product 1

HCID 27351052-(4-nitrophenoxy)tetradecanoyl Chloride

Procedure

An amount of 550 g of 2-(p-nitrophenoxy)-myristic acid is heated together with 550 ml of thionyl chloride for 1 h to 60° C. so that a solution is obtained. The excess thionyl chloride is filtered off. Yield: 585 g (100%) of 2-(p-nitrophenoxyl]-myristoyl chloride (oil).

Workup

  1. customis obtained
  2. filtrationThe excess thionyl chloride is filtered off

Sources & evidence

ORD record
ord-88e05f05acff4e6bba31d87f86060279
Source dataset
uspto-grants-1989_04
Patent number
US04822729

Reaction notes

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