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HRID622641

反应详情

EQUATION

反应方程式

HRID 622641 的结构方程式

REACTANTS

反应物

2
结构：CCCCCCCC/C=C\CCCCCCCC(=O)Cl
HCID5364783

(9Z)-9-Octadecenoyl chloride

C18H33ClO

结构：COC(=O)[C@@H]1CCCN1C(=O)[C@@H](N)CCCCNC(=O)OCc1ccccc1.O=C(O)C(F)(F)F
HCID131667640

未命名化合物

2 次

PRODUCTS

生成物

1
结构：CCCCCCCCCCCCCCCC(=O)N[C@@H](CC(C)C)C(=O)N1CCC[C@H]1C(=O)OC
HCID131715720

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)O
溶剂HCID726987

Benzyloxycarbonyl-L-valine

C13H17NO4

结构：COC(=O)[C@@H]1CCCN1C(=O)[C@H](CC(C)C)NC(=O)[C@@H](N)CC(C)C
溶剂HCID131715721

未命名化合物

PROCEDURE

实验过程

Instead of oleoyl chloride in (b), (a) palmitoyl chloride, (b) stearoyl chloride and (c) linoleolyl chloride were used to obtain (a') palmitoyl-Leu-Pro-OMe (SUAM 1141), (b') stearoyl-Leu-Pro-OMe (SUAM 1142) and (c') linoleoyl-Leu-Pro-OMe (SUAM 1143), respectively. Further, instead of H-Leu-Pro-OMe in (b), (d) H-Val-Pro-OMe, (e) H-Ala-Pro-OMe (f) H-Leu-Leu-Pro-OMe, (g) H-Phe-Pro-OMe, (h) H-Met-Pro-OMe and (i) H-norLeu-Pro-OMe were used to obtain (d') oleoyl-Val-Pro-OMe (SUAM 1147), (e') oleoyl -Ala-Pro-OMe (SUAM 1076), (f') oleoyl-Leu-Leu-Pro-OMe (SUAM 1159), (g') oleoyl-Phe-Pro-OMe (SUAM) 1194), (h') oleoyl-Met-Pro-OMe (SUAM 1198) and (i') oleoyl-norLeu-Pro-OMe (SUAM 1164), as oils, respectively.