HRID622653

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Co+2]

HCID24821

Cobalt nitrate hexahydrate

H12CoN2O12

HCID65237

1,10-Phenanthroline, 2,9-dimethyl-

C14H12N2

HCID522606

Sodium perchlorate

ClNaO4

PRODUCTS

生成物

结构：Cc1ccc2ccc3ccc(C)nc3c2n1.Cc1ccc2ccc3ccc(C)nc3c2n1.Cc1ccc2ccc3ccc(C)nc3c2n1.[Co+3].[O-][Cl+3]([O-])([O-])[O-].[O-][Cl+3]([O-])([O-])[O-].[O-][Cl+3]([O-])([O-])[O-]

HCID86742448

未命名化合物

收率 86%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID22242641

Methanol--water (1/1)

CH6O2

CONDITIONS

反应条件

温度: 4 °C

PROCEDURE

实验过程

Neocuproine (1.00 g, 0.00480 mole) and cobalt (II) nitrate hexahydrate (0.466 g, 0.00160 mole) were dissolved in 30 ml 2:1 water-methanol with stirring in a 60° water bath. Sodium perchlorate solution (3.5 ml 1.5M) was added rapidly with stirring. A flaky pink precipitate was formed immediately. After cooling at 4° C., the product was collected by vacuum filtration and dried in vacuum. Yield=86%. IR: 2800-3700, 1630, 1600, 1570, 1500, 1425, 1390, 1360, 1300, 1030-1150, 860, 730, 625 cm-1.

WORKUP

后处理

stirringwith stirring
customA flaky pink precipitate was formed immediately
filtrationthe product was collected by vacuum filtration
customdried in vacuum

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-8730f0ad45a64c63af98c72162520657
来源数据集: uspto-grants-1988_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04772563
来源说明: uspto-grants-1988_09

反应 SMILES

[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[CH:6]=[CH:7][C:8]3[CH:9]=[CH:10][C:11]([CH3:16])=[N:12][C:13]=3[C:14]=2[N:15]=1.O.O.O.O.O.O.[N+]([O-])([O-])=O.[Co+2:27].[N+]([O-])([O-])=O.[Cl:32]([O-:36])(=[O:35])(=[O:34])=[O:33].[Na+]>O.CO>[Cl:32]([O-:36])(=[O:35])(=[O:34])=[O:33].[Co+3:27].[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[C:14](=[C:13]3[C:8](=[CH:7][CH:6]=2)[CH:9]=[CH:10][C:11]([CH3:16])=[N:12]3)[N:15]=1.[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[C:14](=[C:13]3[C:8](=[CH:7][CH:6]=2)[CH:9]=[CH:10][C:11]([CH3:16])=[N:12]3)[N:15]=1.[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[C:14](=[C:13]3[C:8](=[CH:7][CH:6]=2)[CH:9]=[CH:10][C:11]([CH3:16])=[N:12]3)[N:15]=1.[Cl:32]([O-:36])(=[O:35])(=[O:34])=[O:33].[Cl:32]([O-:36])(=[O:35])(=[O:34])=[O:33]