Bromine → HCID 14822963, compound

HRID 623239Notes

Reaction equation

HRID 623239 reaction equation
[CH2:1]([Sn:11]([CH2:22][C:23]([C:26]1[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1)([CH3:25])[CH3:24])(C1C=CSC=1)[C:12]1[CH:16]=[CH:15][S:14][CH:13]=1)[C:2]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([CH3:4])[CH3:3].[Br:32]Br>>[CH2:1]([Sn:11]([Br:32])([CH2:22][C:23]([C:26]1[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1)([CH3:25])[CH3:24])[C:12]1[CH:16]=[CH:15][S:14][CH:13]=1)[C:2]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([CH3:4])[CH3:3]

Participants

3

Reactant 2

HCID 24408BromineHCID 14822962HCID 14822962, compound

Product 1

HCID 14822963HCID 14822963, compound

Procedure

In substantial accordance with the procedure described in Example 1(2), dineophyl-di(3-thienyl)tin (80 g, 0.145 mol) obtained above was reacted with bromine to give crude dineophyl-3-thienyltin bromide, which was then reacted with sodium fluoride. The resulting product was recrystallized from n-hexane to provide 21.5 g of dineophyl-3-thienyltin fluoride as a white solid.

Workup

  1. customobtained

Sources & evidence

ORD record
ord-24f2e60d6b2c4b118ee2fa75b4bb58fb
Source dataset
uspto-grants-1988_09
Patent number
US04774235

Reaction notes

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