(4-Methoxyphenyl)boronic acid → 4-(4-Methoxy-phenyl)-indene

HRID 627809Notes

Reaction equation

HRID 627809 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6](B(O)O)=[CH:5][CH:4]=1.C[Si](C)(C)C1C=CC([C:20]2[CH:28]=[CH:27][CH:26]=[C:25]3[C:21]=2[CH:22]=[CH:23][CH2:24]3)=CC=1>>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([C:20]2[CH:28]=[CH:27][CH:26]=[C:25]3[C:21]=2[CH:22]=[CH:23][CH2:24]3)=[CH:5][CH:4]=1

Participants

3

Reactant 2

HCID 201262(4-Methoxyphenyl)boronic acidHCID 867251604-(4-Trimethylsilyl-phenyl)-indene

Product 1

HCID 867251624-(4-Methoxy-phenyl)-indeneYield 89%

Procedure

The synthesis was performed by the same procedure as in Metallocene Compound A (1-1) by using 4-methoxyphenylboronic acid in place of 4-trimethylsilylphenylboronic acid in the synthesis of 4-(4-trimethylsilyl-phenyl)-indene to obtain a yellow liquid of 4-(4-methoxy-phenyl)-indene in a yield of 89%.

Sources & evidence

ORD record
ord-74fee19bba6d4459b3d5d1bf029eab73
Source dataset
uspto-grants-2016_04
Patent number
US09309340B2

Reaction notes

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