Sodium hexafluoroantimonate → HCID 19734742, compound

HRID 6285Notes

Reaction equation

HRID 6285 reaction equation
F[B-](F)(F)F.[CH3:6][C:7]1[CH:30]=[CH:29][C:10]([CH2:11][S+:12]([CH2:21][C:22]2[CH:27]=[CH:26][C:25]([CH3:28])=[CH:24][CH:23]=2)[CH2:13][C:14]2[CH:19]=[CH:18][C:17]([CH3:20])=[CH:16][CH:15]=2)=[CH:9][CH:8]=1.[F:31][Sb-:32]([F:37])([F:36])([F:35])([F:34])[F:33].[Na+]>>[F:31][Sb-:32]([F:37])([F:36])([F:35])([F:34])[F:33].[CH3:20][C:17]1[CH:18]=[CH:19][C:14]([CH2:13][S+:12]([CH2:11][C:10]2[CH:9]=[CH:8][C:7]([CH3:6])=[CH:30][CH:29]=2)[CH2:21][C:22]2[CH:27]=[CH:26][C:25]([CH3:28])=[CH:24][CH:23]=2)=[CH:15][CH:16]=1

Participants

3

Reactant 2

HCID 16689647Sodium hexafluoroantimonateHCID 19795292Tris(p-methylbenzyl)sulfonium tetrafluoroborate

Product 1

HCID 19734742HCID 19734742, compoundYield 87.3%

Procedure

Analogously to Example 4c), 100 g (230 mmol) of tris(p-methylbenzyl)sulfonium tetrafluoroborate are reacted with 119.0 g (460 mmol) of sodium hexafluoroantimonate. Recrystallization in isopropanol gives 117.1 g (87% of theory) of tris(p-methylbenzyl)sulfonium hexafluoroantimonate in the form of white crystals of melting point 88°-91° C.

Workup

  1. customRecrystallization in isopropanol

Sources & evidence

ORD record
ord-dcb6757025c842f682ae2753a298d10d
Source dataset
uspto-grants-1993_09
Patent number
US05247113

Reaction notes

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