1-(((1-Naphthylmethyl)thio)methyl)naphthalene → Bis(1-naphthylmethyl)ethylsulfonium hexafluoroantimonate

HRID 6289Notes

Reaction equation

HRID 6289 reaction equation
[C:1]1([CH2:11][S:12][CH2:13][C:14]2[C:23]3[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=3)[CH:17]=[CH:16][CH:15]=2)[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1.[F:24][Sb-:25]([F:30])([F:29])([F:28])([F:27])[F:26].[CH2:31]([O+](CC)CC)[CH3:32]>C(Cl)Cl>[F:24][Sb-:25]([F:30])([F:29])([F:28])([F:27])[F:26].[C:1]1([CH2:11][S+:12]([CH2:13][C:14]2[C:23]3[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=3)[CH:17]=[CH:16][CH:15]=2)[CH2:31][CH3:32])[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 2339071-(((1-Naphthylmethyl)thio)methyl)naphthaleneHCID 22239852Triethyloxonium hexafluoroantimonate

Product 1

HCID 19795277Bis(1-naphthylmethyl)ethylsulfonium hexafluoroantimonateYield 98.5%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

5.0 g (15.9 mmol) of bis(1-naphthylmethyl) sulfide and 5.93 g (17.5 mmol) of triethyloxonium hexafluoroantimonate in 30 ml of methylene chloride are reacted according to Example 1a) to give 9.07 g (98% of theory) of bis(1-naphthylmethyl)ethylsulfonium hexafluoroantimonate in the form of white crystals of melting point 101°-105° C.

Sources & evidence

ORD record
ord-b72b1df24dfd40c49dba15fa1f93e2ed
Source dataset
uspto-grants-1993_09
Patent number
US05247113

Reaction notes

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