4-Bromobenzaldehyde → Benzaldehyde, 4-pentyl-

HRID 629147Notes

Reaction equation

HRID 629147 reaction equation
Br[C:2]1[CH:9]=[CH:8][C:5]([CH:6]=[O:7])=[CH:4][CH:3]=1.[CH2:10](B(O)O)[CH2:11][CH2:12][CH2:13][CH3:14]>>[CH2:10]([C:2]1[CH:9]=[CH:8][C:5]([CH:6]=[O:7])=[CH:4][CH:3]=1)[CH2:11][CH2:12][CH2:13][CH3:14]

Participants

3

Reactant 2

HCID 707414-BromobenzaldehydeHCID 352103Pentylboronic Acid

Product 1

HCID 23290Benzaldehyde, 4-pentyl-Yield 68%

Procedure

The compound was synthesized as in Example 3.1 using 4-bromobenzaldehyde (250 mg, 1.35 mmol) in place of 5-bromo-2-formylfuran and pentylboronic acid (259 mg, 2.23 mmol) in place of hexylboronic acid to give 4-pentylbenzaldehyde (161 mg, 68%). Used without further characterization.

Sources & evidence

ORD record
ord-192b21b309ac4e928974af51fd081225
Source dataset
uspto-grants-2016_04
Patent number
US09315495B2

Reaction notes

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