Methyl Ethyl Ketone → HCID 21260823, compound

HRID 634877Notes

Reaction equation

HRID 634877 reaction equation
[OH:1][C:2]1[CH:7]=[CH:6][C:5]([CH2:8][C:9]([O:11][CH3:12])=[O:10])=[CH:4][CH:3]=1.C(=O)([O-])[O-].[K+].[K+].[CH3:19][C:20](=O)[CH2:21][CH3:22]>>[CH2:19]([O:1][C:2]1[CH:3]=[CH:4][C:5]([CH2:8][C:9]([O:11][CH3:12])=[O:10])=[CH:6][CH:7]=1)[CH2:20][CH2:21][CH2:22][CH2:8][CH2:5][CH2:6][CH2:7][CH2:2][CH:3]=[CH2:4]

Participants

4

Reactant 3

HCID 6569Methyl Ethyl KetoneHCID 11430Potassium CarbonateHCID 518900Benzeneacetic acid, 4-hydroxy-, methyl ester

Product 1

HCID 21260823HCID 21260823, compound

Procedure

A solution of methyl (4-hydroxyphenyl)ethanoate (7.50 g, 45 mmol)1-bromoudec-10-ene (10 g, 43 mmol) and potassium carbonate (7.50 g, 54 mmol) in butanone (250 ml) was heated under reflux (12 h). The solvent was removed in vacuo to yield a pale yellow oil.

Workup

  1. temperatureunder reflux (12 h)
  2. customThe solvent was removed in vacuo
  3. customto yield a pale yellow oil

Sources & evidence

ORD record
ord-5a015a4bb8964ffaa5c9b05ea0ab07d5
Source dataset
uspto-grants-2001_02
Patent number
US06184322B2

Reaction notes

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