HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tetrahydrofuran → (3-Tert-butyl-2-methoxy-5-ethylphenyl)dimethyl(tetramethylcyclopentadienyl)silane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tetrahydrofuran | HCID 8028 | — |
| Reactant | (2-Methoxy-3-tert-butyl-5-methylphenyl)chlorodimethylsilane | HCID 11032947 | — |
| Reactant | Lithium tetramethylcyclopentadienide | HCID 178506838 | — |
| Product | (3-Tert-butyl-2-methoxy-5-ethylphenyl)dimethyl(tetramethylcyclopentadienyl)silane | HCID 131722375 | — |
Reaction Steps
To a solution of (3-tert-butyl-2-methoxy-5-methylphenyl)chlorodimethylsilane (5.24 g) synthesized in the above (3) and tetrahydrofuran (50 ml), tetramethylcyclopentadienyl lithium (2.73 g) was added at −35° C. and the mixture was heated to room temperature over 2 hours, followed by stirring at room temperature for 10 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06184319B2 |
| Source dataset | uspto-grants-2001_02 |
| ORD ID | ord-440b0fd3f3e74778924a7df8cc9b24b5 |
| Source note | uspto-grants-2001_02 |