Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3,4-dihydro-2H-pyran → 2H-Pyran, 2-[(12-bromododecyl)oxy]tetrahydro-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3,4-dihydro-2H-pyran | HCID 8080 | — |
| 반응물 | 12-Bromo-1-dodecanol | HCID 137895 | — |
| 반응물 | Benzenesulfonic acid, 4-methyl-, compd. with pyridine (1:1) | HCID 466102 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 2H-Pyran, 2-[(12-bromododecyl)oxy]tetrahydro- | HCID 11078592 | — |
반응 단계
To a solution of 12-bromo-1-dodecanol (1 mole) in dichloromethane containing pyridinium p-toluenesulfonate (P-TSA) is added dihydropyran (2 moles). The reaction mixture is stirred for 24 hours and then washed twice with water and dried over anhydrous MgSO4. The dichloromethane is removed under reduced pressure. If necessary the resulting product is purified by chromatography on silica gel.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06191105B1 |
| 출처 데이터셋 | uspto-grants-2001_02 |
| ORD ID | ord-4d804cb2e89a4d62a903166886d19112 |
| 출처 메모 | uspto-grants-2001_02 |