40137-00-6 → HCID 11042011, compound

HRID 637569Notes

Reaction equation

HRID 637569 reaction equation
[CH2:1]([N:3]([CH2:6]/[CH:7]=[C:8](/[CH3:15])\[CH2:9][CH2:10][CH:11]=[C:12]([CH3:14])[CH3:13])[CH2:4][CH3:5])[CH3:2]>O1CCCC1>[CH2:1]([N:3](/[CH:6]=[CH:7]/[C@H:8]([CH3:15])[CH2:9][CH2:10][CH:11]=[C:12]([CH3:13])[CH3:14])[CH2:4][CH3:5])[CH3:2]

Participants

3

Reactant 1

HCID 624334340137-00-6

Product 1

HCID 11042011HCID 11042011, compoundYield 104.1%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

1.14 g (5.0 mmol) of (Z)-N,N-diethyl-3,7-dimethyl-2,6-octadienylamine, 5 ml of tetrahydrofuran and 16 mg (0.0192 mmol) of [η4 -bicyclo[2.2.1]hepta-2,5-diene][(R)-(6,6'-dimethyl-2,2'-biphenylylene)-bis(diphenylphosphine)]rhodium (I) tetrafluoroborate were placed in a Pyrex bomb tube under nitrogen. After degasifying the mixture, the tube was sealed and heated in a bomb tube oven at 85° C. to 90° C. for 19 hours. The brownish-red mixture was evaporated and the residue was distilled in a bulb-tube at about 120° C./0.05 mmHg. There were obtained 1.09 g of (1E,3R)-N,N-diethyl-3,7-dimethyl-1,6-octadienylamine as a colourless distillate.

Workup

  1. customthe tube was sealed
  2. temperatureheated in a bomb tube oven at 85° C. to 90° C. for 19 hours
  3. customThe brownish-red mixture was evaporated
  4. distillationthe residue was distilled in a bulb-tube at about 120° C./0.05 mmHg

Sources & evidence

ORD record
ord-81f9c4d56cb34bdfa9fac2d14d48c0eb
Source dataset
uspto-grants-1985_12
Patent number
US04556740

Reaction notes

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