Dimethylformamide → HCID 12881468, compound

HRID 637904Notes

Reaction equation

[CH3:1][O:2][C:3]1[C:4]([OH:25])=[C:5]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][C:21]([O:23][CH3:24])=[O:22])[C:6]([CH3:11])=[CH:7][C:8]=1[O:9][CH3:10].CN(C)C=[O:29]>>[CH3:1][O:2][C:3]1[C:4](=[O:25])[C:5]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][C:21]([O:23][CH3:24])=[O:22])=[C:6]([CH3:11])[C:7](=[O:29])[C:8]=1[O:9][CH3:10]

Participants

Reactant 2

HCID 6228Dimethylformamide

HCID 12824095Methyl 10-(2-hydroxy-3,4-dimethoxy-6-methylphenyl)decanoate

Product 1

HCID 12881468HCID 12881468, compound

Procedure

A dimethylformamide solution of methyl 10-(3,4-dimethoxy-2-hydroxy-6-methylphenyl)decanoate (129 mg) is oxidized in the same manner as Example 20. This procedure yields 2,3-dimethoxy-5-methyl-6-(9-methoxycarbonylnonyl)-1,4-benzoquinone (91 mg) as orange-yellow needles melting at 37° C.-38° C.

Sources & evidence

ORD record: ord-abdd13f9060e44d9a7e8be23763568e1
Source dataset: uspto-grants-1985_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04559177

Reaction notes

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