N-methyl-2-pyrrolidone → S-octadecyl thiocarbamate

HRID 6410Notes

Reaction equation

[CH2:1]([SH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].C[N:21]1CCC[C:22]1=[O:26]>>[C:22](=[O:26])([S:19][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[NH2:21]

Participants

Reactant 2

HCID 13387N-methyl-2-pyrrolidone

HCID 179051-Octadecanethiol

Product 1

HCID 18997609S-octadecyl thiocarbamateYield 60%

Procedure

As described in Example 17, but using 63 g of 1-octadecylmercaptan (0.22 mol) dissolved in 30 ml of N-methylpyrrolidone, S-octadecyl thiocarbamate was obtained in a yield of 60% of theory.

Sources & evidence

ORD record: ord-708d04ef70ce40fc929d6ad0b2ca124d
Source dataset: uspto-grants-1993_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05248755

Reaction notes

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