HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Benzyl-2-methyl-1H-pyrrole-3-carboxylic acid ethyl ester → 1-Benzyl-4,5-dibromo-2-bromomethyl-1H-pyrrole-3-carboxylic acid ethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Benzyl-2-methyl-1H-pyrrole-3-carboxylic acid ethyl ester | HCID 10728933 | — |
| Reactant | 4,5-dibromo-2-bromomethyl-1-phenyl-1H-pyrrole-3-carboxylic acid ethyl ester | HCID 68426531 | — |
| Product | 1-Benzyl-4,5-dibromo-2-bromomethyl-1H-pyrrole-3-carboxylic acid ethyl ester | HCID 68426368 | — |
Reaction Steps
Prepared in analogy to that of 4,5-dibromo-2-bromomethyl-1-phenyl-1H-pyrrole-3-carboxylic acid ethyl ester (Example 1(a)) from 1-benzyl-2-methyl-1H-pyrrole-3-carboxylic acid ethyl ester; the title product, 1H NMR (200 MHz, CDCl3): δ (ppm)=7.30 (m, 3H), 7.00 (m, 2H), 5.40 (s, 2H), 4.77 (s, 2H), 4.35 (q, 2H, J=6.8 Hz), 1.40 (t, 3H, J=6.8 Hz).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07696223B2 |
| Source dataset | uspto-grants-2010_04 |
| ORD ID | ord-ee9713fe23bc4e0fbd8dfa33e965ca54 |
| Source note | uspto-grants-2010_04 |