Ammonium Chloride → HCID 86761087, compound

HRID 644575Notes

Reaction equation

HRID 644575 reaction equation
C([Si]([O:8][C:9]1[CH:14]=[CH:13][CH:12]=[C:11](/[C:15](/[CH2:19][CH3:20])=[CH:16]/[C:17]#[CH:18])[CH:10]=1)(C)C)(C)(C)C.[F-].C([N+](CCCC)(CCCC)CCCC)CCC.[Cl-].[NH4+]>C1COCC1>[CH2:19](/[C:15](/[C:11]1[CH:10]=[C:9]([OH:8])[CH:14]=[CH:13][CH:12]=1)=[CH:16]\[C:17]#[CH:18])[CH3:20]

Participants

5

Reactant 3

HCID 25517Ammonium ChlorideHCID 2724141Tetrabutylammonium FluorideHCID 86761086HCID 86761086, compound

Product 1

HCID 86761087HCID 86761087, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

1 g (3.5 mmol) of tert-butyl-[3-((E)-1-ethylbut-1-en-3-ynyl)phenoxy]dimethylsilane is dissolved in 50 ml of THF, and 3.8 ml (38 mmol) of a 1.0 M solution of tetrabutylammonium fluoride are added drop by drop. The mixture is stirred for 30 minutes, then treated with a saturated solution of ammonium chloride and extracted with ethyl acetate. A yellow oil is obtained (m=690 mg; Y=100%).

Workup

  1. extractionextracted with ethyl acetate
  2. customA yellow oil is obtained (m=690 mg; Y=100%)

Sources & evidence

ORD record
ord-0388b8b0163644c48977a31e787b087e
Source dataset
uspto-grants-2010_04
Patent number
US07700657B2

Reaction notes

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