Aluminium lithium hydride → HCID 67456487, compound

HRID 645310Notes

Reaction equation

HRID 645310 reaction equation
[H-].[H-].[H-].[H-].[Li+].[Al+3].C([O:9][C:10]([C:12]1[C:21]2[C:16](=[CH:17][C:18]([C:22]3[CH:27]=[CH:26][C:25]([O:28][CH2:29][CH2:30][CH:31]([CH3:38])[CH2:32][CH2:33][CH2:34][CH:35]([CH3:37])[CH3:36])=[CH:24][CH:23]=3)=[CH:19][CH:20]=2)[C:15]([C:39](OCC)=[O:40])=[CH:14][CH:13]=1)=O)C>C1COCC1>[OH:9][CH2:10][C:12]1[C:21]2[C:16](=[CH:17][C:18]([C:22]3[CH:27]=[CH:26][C:25]([O:28][CH2:29][CH2:30][CH:31]([CH3:38])[CH2:32][CH2:33][CH2:34][CH:35]([CH3:37])[CH3:36])=[CH:24][CH:23]=3)=[CH:19][CH:20]=2)[C:15]([CH2:39][OH:40])=[CH:14][CH:13]=1

Participants

4

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 68421412HCID 68421412, compound

Product 1

HCID 67456487HCID 67456487, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent2×

Procedure

Under argon atmosphere and with cooling in ice, 10.0 ml of THF solutions of LiAlH4 (1.0M) was added to 6-(4-(3,7-dimethyloctyloxy)phenyl)naphthalene-1,4-dicarboxylic-acid diethyl ester 1.42 g in THF solution, and stirred at a temperature as it was, for 3 hours.

Workup

  1. temperatureUnder argon atmosphere and with cooling in ice

Sources & evidence

ORD record
ord-98e26d7bbd714bf4a9977a9c0c0b5602
Source dataset
uspto-grants-2010_04
Patent number
US07701129B2

Reaction notes

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