beta-Methylstyrene → HCID 17842075, compound

HRID 645336Notes

Reaction equation

HRID 645336 reaction equation
[CH:1]1([CH2:4][C:5]2[CH:10]=[CH:9][C:8]([OH:11])=[C:7]([O:12][CH3:13])[CH:6]=2)[CH2:3][CH2:2]1.[CH:14]1([CH2:17][C:18]2[CH:23]=[CH:22][C:21]([O:24]C)=[C:20]([O:26][CH3:27])[CH:19]=2)[CH2:16][CH2:15]1.C(C1C=CC=CC=1)=CC>>[CH3:13][O:12][C:7]1[CH:6]=[C:5]([CH:4]2[CH2:1][CH:3]2[CH3:2])[CH:10]=[CH:9][C:8]=1[OH:11].[CH3:15][CH:16]1[CH2:14][CH:17]1[C:18]1[CH:23]=[CH:22][C:21]2[O:24][CH2:27][O:26][C:20]=2[CH:19]=1

Participants

5

Reactant 3

HCID 12500beta-MethylstyreneHCID 17842076HCID 17842076, compoundHCID 17842078HCID 17842078, compound

Product 2

HCID 17842075HCID 17842075, compoundHCID 68616131HCID 68616131, compound

Procedure

4-Cyclopropylmethyl-2-methoxy-phenol (B); 4-Cyclopropylmethyl-1,2-dimethoxy-benzene (C); 2-Methoxy-4-(2-methyl-cyclopropyl)-phenol (D) and 5-(2-methyl-cyclopropyl)-benzo[1,3]dioxole (E) were synthesised by reacting the corresponding propenyl benzene in a procedure analogous to that of Example 1.

Sources & evidence

ORD record
ord-bd8ec364a71f4ceeb155410882197cd8
Source dataset
uspto-grants-2010_04
Patent number
US07704942B2

Reaction notes

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