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HRID647129

反应详情

EQUATION

反应方程式

HRID 647129 的结构方程式

REACTANTS

反应物

3
结构：Cl
HCID313

Hydrochloric Acid

ClH

结构：O
HCID962

Water

H2O

结构：CC1(C)NC(=O)N(c2ccc(Cl)c(C(F)(F)F)c2)C1=N
HCID3054080

1-[4-Chloro-3-(trifluoromethyl)phenyl]-5-imino-4,4-dimethyl-4,5-dihydro-1H-imidazol-2-ol

C12H11ClF3N3O

PRODUCTS

生成物

1
结构：CC1(C)NC(=O)N(c2ccc(Cl)c(C(F)(F)F)c2)C1=O
HCID3054078

2,4-Imidazolidinedione, 3-(4-chloro-3-(trifluoromethyl)phenyl)-5,5-dimethyl-

C12H10ClF3N2O2

PROCEDURE

实验过程

61 mg. of 1-(3-trifluoromethyl-4-chlorophenyl)-5-imino-4,4-dimethyl-2-imidazolidinone are dissolved in 4 ml. of 0.1-N aqueous hydrochloric acid, and 2 ml. of water are added. The white needles which gradually precipitate are removed by filtration after 20 hours, washed with water and dried under greatly reduced pressure at 65° for 2 hours. 3-(3-trifluoromethyl-4-chlorophenyl)-5,5-dimethylhydantoin, which melts at 156°-157.5°, is obtained.

WORKUP

后处理

  1. customThe white needles which gradually precipitate are removed by filtration after 20 hours
  2. washwashed with water
  3. customdried under greatly reduced pressure at 65° for 2 hours