Morpholine → HCID 13654955, compound

HRID 648910Notes

Reaction equation

HRID 648910 reaction equation
[NH:1]1[CH2:6][CH2:5][O:4][CH2:3][CH2:2]1.[Br-:7].C[C:9]1[S:13][CH:12]=[CH:11][S+:10]=1>C(O)C>[Br-:7].[S:10]1[CH:11]=[CH:12][S:13][C:9]1=[N+:1]1[CH2:6][CH2:5][O:4][CH2:3][CH2:2]1

Participants

4

Reactant 2

HCID 8083MorpholineHCID 20144154HCID 20144154, compound

Product 1

HCID 13654955HCID 13654955, compoundYield 86.6%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

1.0 g of morpholine and 2.3 g of 2-methyl-1,3-dithiolium bromide were treated in the same manner as in Example 26, and the product was recrystallized from ethanol, whereby 2.2 g (yield: 86.6%) of 4-(1,3-dithiol-2-ylidene)morpholinium bromide (Compound No. 28) was obtained as crystals having a melting point of 274° to 276° C.

Sources & evidence

ORD record
ord-a6dbf040adb24727875bae4388f7595b
Source dataset
uspto-grants-1988_04
Patent number
US04737494

Reaction notes

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