Pyrrolidine → HCID 13654962, compound

HRID 648916Notes

Reaction equation

HRID 648916 reaction equation
[NH:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[Cl:6]([O-:10])(=[O:9])(=[O:8])=[O:7].CS[C:13]1[S:17][CH:16]=[CH:15][S+:14]=1>>[Cl:6]([O-:10])(=[O:9])(=[O:8])=[O:7].[S:14]1[CH:15]=[CH:16][S:17][C:13]1=[N+:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1

Participants

3

Reactant 2

HCID 31268PyrrolidineHCID 230390092-Methylthio-1,3-dithiolium perchlorate

Product 1

HCID 13654962HCID 13654962, compoundYield 55.3%

Procedure

0.9 ml of pyrrolidine and 2.5 g of 2-methylthio-1,3-dithiolium perchlorate were treated in the same manner as in Example 26, and the product was recrystallized from acetone-ethyl ether, whereby 1.5 g (yield: 55.3%) of 1-(1,3-dithiol-2-ylidene)pyrrolidinium perchlorate (Compound No. 35) was obtained as crystals having a melting point of 216° C.

Workup

  1. customthe product was recrystallized from acetone-ethyl ether

Sources & evidence

ORD record
ord-1b38adf1f111403885be4b6d2efbf05f
Source dataset
uspto-grants-1988_04
Patent number
US04737494

Reaction notes

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