Cyclohexanone → HCID 13710012, compound

HRID 64941Notes

Reaction equation

HRID 64941 reaction equation
[C:1]([C:5]1[CH:10]=[C:9]([SH:11])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:4])([CH3:3])[CH3:2].[C:17]1(=[O:23])[CH2:22][CH2:21][CH2:20][CH2:19][CH2:18]1>CO>[C:1]([C:5]1[CH:10]=[C:9]([S:11][C:9]2([S:11][C:20]3[CH:21]=[C:22]([C:1]([CH3:3])([CH3:2])[CH3:4])[C:17]([OH:23])=[C:18]([C:12]([CH3:15])([CH3:14])[CH3:13])[CH:19]=3)[CH2:10][CH2:5][CH2:6][CH2:7][CH2:8]2)[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 7967CyclohexanoneHCID 703702,6-Di-tert-butyl-4-mercaptophenol

Product 1

HCID 13710012HCID 13710012, compoundYield 93.3%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

The procedure of Example 1 was repeated using 28.71 grams of 2.6-di-tert-butyl-4-mercaptophenol, 5.91 grams of cyclohexanone, and 150 ml of methyl alcohol. The product is triturated with methyl alcohol to give 31.17 grams (93.3% yield) of white solid, mp 195°-197° C.

Workup

  1. customThe product is triturated with methyl alcohol

Sources & evidence

ORD record
ord-49ac09a1bc5c4585ae64f08ade600ca0
Source dataset
uspto-grants-1986_09
Patent number
US04611023

Reaction notes

Loading…