Methanol → HCID 20141318, compound

HRID 649442Notes

Reaction equation

HRID 649442 reaction equation
C[S:2][C:3](=S)[NH:4][S:5]([C:8]1[CH:13]=[CH:12][C:11]([Cl:14])=[CH:10][CH:9]=1)(=[O:7])=[O:6].[CH3:16][OH:17]>>[CH3:16][O:17][C:3](=[S:2])[NH:4][S:5]([C:8]1[CH:13]=[CH:12][C:11]([Cl:14])=[CH:10][CH:9]=1)(=[O:7])=[O:6]

Participants

3

Reactant 2

HCID 887MethanolHCID 13048266HCID 13048266, compound

Product 1

HCID 20141318HCID 20141318, compound

Procedure

14.1 g of N-(4-chlorophenylsulfonyl)-dithiocarbamic acid-S-methyl ester (0.05 mol) are refluxed in 100 ml of methanol, and after about 5 hours the formation of mercaptan has finished. The solvent is distilled off in a rotary evaporator, and the residue is recrystallised from methanol; yield 116 g (87% of theory), m.p. 129°-130° C.

Workup

  1. distillationThe solvent is distilled off in a rotary evaporator
  2. customthe residue is recrystallised from methanol

Sources & evidence

ORD record
ord-c7467cdf61594a8d999b1da81b17d449
Source dataset
uspto-grants-1988_04
Patent number
US04740236

Reaction notes

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