2,2'-Azobis(2-methylpropanimidamide) dihydrochloride → HCID 86757238, compound

HRID 650130Notes

Reaction equation

HRID 650130 reaction equation
[Br-:1].[CH2:2]([N+:5]1([CH2:15][CH:16]=[CH2:17])[CH2:14][CH2:13][C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[CH2:6]1)[CH:3]=[CH2:4].[Cl-:18].[CH2:19]([NH2+:22][CH2:23][CH:24]=[CH2:25])[CH:20]=[CH2:21].Cl.Cl.N(C(C(=N)N)(C)C)=NC(C(=N)N)(C)C>O>[Br-:1].[CH2:15]([N+:5]1([CH2:2][CH:3]=[CH2:4])[CH2:14][CH2:13][C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[CH2:6]1)[CH:16]=[CH2:17].[Cl-:18].[CH2:19]([NH2+:22][CH2:23][CH:24]=[CH2:25])[CH:20]=[CH2:21]

Participants

5

Reactant 3

HCID 763442,2'-Azobis(2-methylpropanimidamide) dihydrochlorideHCID 108987626147-66-6HCID 15551879HCID 15551879, compound

Product 1

HCID 86757238HCID 86757238, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
70 °C

Procedure

N,N-diallyl 1,2,3,4-tetrahydroisoquinolinium bromide (15.0 g, EXAMPLE 5), and diallylammonium chloride (2.9 9, EXAMPLE 7) were dissolved in 18 mL deionized water. To this aqueous solution was added 0.5 g of 2,2′-azobis(2-amidinopropane) dihydrochloride, and the reaction mixture was bubbled with a slow stream of nitrogen gas for 45 minutes. While stirring, the temperature was raised to 70° C. The reaction mixture was stirred at 70° C. for 48 hours. After cooling to room temperature, 34.0 9 of viscous polymer solution was obtained.

Workup

  1. customthe reaction mixture was bubbled with a slow stream of nitrogen gas for 45 minutes
  2. stirringThe reaction mixture was stirred at 70° C. for 48 hours
  3. temperatureAfter cooling to room temperature
  4. custom34.0 9 of viscous polymer solution was obtained

Sources & evidence

ORD record
ord-8534f42598324e759b73db7d288aa3dc
Source dataset
uspto-grants-2001_08
Patent number
US06271264B1

Reaction notes

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