HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 69986732, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 4-Iodoanisole | HCID 69676 | — |
| Reactant | 1H-Benz[e]indene | HCID 11745004 | — |
| Catalyst | palladium(II) acetate | HCID 167845 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 69986732 | HCID 69986732 | 54% |
Reaction Steps
20 mnl of triethylamine, 3.32 g (20 mmole) of benzindene, 4.68 g (20 mmole) of p-methoxy-phenyl-iodide and 0.134 g (0.6 mmole) of Pd(OAc)2 were stirred under reflux for 10 h. After that the mixture was cooled to room temperature and treated with 100 ml of ethanol. The crystalline precipitate was isolated, washed with ethanol and dried under vacuum to obtain 2.9 g (54%) of the mixture of two isomers.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06271411B1 |
| Source dataset | uspto-grants-2001_08 |
| ORD ID | ord-91e75c7ed70442589cc2e5ef06b8913c |
| Source note | uspto-grants-2001_08 |