HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Disulfide → HCID 13375551, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Disulfide | HCID 6348 | — |
| Reactant | 1-Chloro-4-(chloromethyl)benzene | HCID 7723 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | HCID 13863924 | HCID 13863924 | — |
| Solvent | Ethanol | HCID 702 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | HCID 13375551 | HCID 13375551 | 34% |
Reaction Steps
In the same manner as described in Example 13 by using (3R)-3-(2-hydroxyethyl)-1,2,3,4-tetrahydro-β-carboline (100 mg), 2N NaOH (0.23 ml), CS2 (0.028 ml), 4-chlorobenzyl chloride (82 mg) and 70% ethanol (2.5 ml), there is prepared the title compound (66 mg, 34%) as white powder, [α]D20 -115.8° (c=1.0, ethyl acetate). Mass m/e: 416 (M+), 258 (M+ --p--Cl--C6H4 --CH2SH).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04612317 |
| Source dataset | uspto-grants-1986_09 |
| ORD ID | ord-c9da69fba55d41bd81f2e1894fd58568 |
| Source note | uspto-grants-1986_09 |